Равновесие между жидкостью и паром Книга 1 - Коган В.Б.
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79.5 90.4 73.7 83.5 56.85 57.84 5.0 61.3 j 63.0 73.78
100.0 100.0 60.77 66.2 64.0 73.81
0.0 0.0 93.52 600 79.5 68.3 74.26
2.0 46.0 74.40 90.4 80.5 75.73
3.0 54.2 70.92 100.0 100.0 79.64
Примечание. Скобкой отмечены сосуществующие жидкие фазы.
№ 372 ВОДА—МАСЛЯНАЯ КИСЛОТА
C4HeO2
H2O-C4HfiO2
[823]
X У t P X У t P
0 0.0 163.5 760 60 90.8 760
2 16.0 — 70 91.4 —
5 39.5 — 80 91,6 —
10 57.7 — 85 92.1 —
20 76.2 — 90 92.9 —
30 83.4 — 95 94.8 —
40 87.8 — 98 97.1 —
50 90.0 — 100 100.0 100.0
ВОДА—МАСЛЯНАЯ КИСЛОТА
II2O-C4H8O2
t = 25
0.074
[585]
, = *А ^f + 0,25 - ^f + 0.85) + е-^--) X
X
0.07 1.6
1.6
Ig W = (I-J2 [0-725 + 0.85 Г11-^ + 1.61 в-23«1-^)],
где хд — молярная доля кислоты в жидкой фазе.
315 JVs 374 ВОДА—МАСЛЯНАЯ КИСЛОТА [6]
H2O-C4HeO2
X У t P X У t P
0.0 0.0 163.9 760 70.0 93.8 100.4 760
14.8 73.4 120.8 80.0 94.2 99.8
20.0 81.0 116.4 90.0 94.9 99.7
33.1 87.9 109.5 97.9 96.8 99.4
56.2 91.9 103.5 100.0 100.0 100.0
JVs 375 ВОДА- -МАСЛЯНАЯ КИСЛОТА [913]
H2O-C4Il8O2
X У t P X У t P
0.0 0.0 163.2 760 25.5 84.3 105.0 600
1.4 12.5 158.6 31.5 87.2 102.4
4.1 40.6 147.4 32.9 88.0 101.6
5.2 50.4 143.5 35.2 88.8 100.9
6.5 52.2 143.1 40.2 89.7 99.5
12.5 72.8 126.3 47.1 91.1 97.5
21.0 81.8 115.5 50.3 91.9 96.6
29.0 86.0 110.0 53.7 92.4 96.1
33.0 87.7 108.9 62.1 93.4 94.7
33.7 87.5 108.5 65.5 93.7 94.4
36.6 88.2 107.2 67.7 93.9 94.2
46.0 90.5 104.5 72.1 94.3 93.9
49.8 91.2 103.8 79.5 94.9 93.5
52.7 91.6 102.9 83.0 95.0 93.5
61.5 92.9 101.0 89.4 95.3 93.2
66.4 93.5 100.8 93.3 95.7 93.1
68.9 94.0 100.3 95.9 95.9 93.1
79.7 94.6 100.1 96.4 96.1 93.1
83.5 94.8 100.0 97.5 96.6 93.1
84.1 94.9 99.9 97.8 96.8 93.1
89.2 95.2 99.7 100.0 100.0 93.5
93.7 95.5 99.6 0.0 0.0 143.2 400
95.7 95.8 99.6 2.6 33.0 132.1
95.9 95.8 99.6 2.8 36.6 130.0
96.3 95.9 99.6 6.5 49.8 122.8
97.2 96.4 99.6 6.6 61.4 116.6
98.0 96.9 99.6 10.3 75.2 107.2
100.0 100.0 100.0 21.0 85.0 96.3
0.0 0.0 155.5 600 29.7 88.0 92.0
1.4 12.5 151.3 35.2 89.6 89.5
2.8 36.6 140.0 37.3 90.4 88.7
6.5 55.0 136.2 40.2 91.1 87.8
7.9 64.6 125.5 47.1 92.1 86.4
17.9 80.8 110.0 53.7 93.1 85.4
21.0 82.4 108.3 58.8 93.7 84.5 Таблица JNs 446 (продолжение)
X У t P X У t P
62.8 94.1 84.0 400 93.0 96.2 66.2 200
67.7 94.5 83.4 96.1 96.5 66.2
70.8 94.7 83.3 96.8 96.6 66.2
78.7 95.1 83.0 97.0 96.8 66.2
84.0 95.4 82.9 97.8 97.2 66.2
89.0 95.6 82.7 100.0 100.0 66.4
93.2 95.8 82.6 0.0 0.0 107.8 100
95.9 96.1 82.6 1.4 38.0 99.9
96.0 96.1 82.6 2.8 53.2 94.2
96.1 96.1 82.6 4.1 64.2 87.4
97.3 96.6 82.6 6.5 79.4 74.6
97.8 96.9 82.6 21.0 90.2 60.4
100.0 100.0 83.0 22.9 90.7 60.0
0.0 0.0 125.2 200 28.9 91.2 58.1
1.4 12.6 121.2 35.2 92.7 55.6
2.7 41.9 111.2 39.9 93.4 55.1
4.0 53.6 106.4 45.4 93.8 54.3
6.5 59.2 102.9 47.6 94.1 54.0
9.0 71.3 94.3 51.2 94.3 53.5
11.4 75.6 90.1 52.7 94.7 53.2
12.6 81.6 84.2 59.9 95.3 52.8
15.9 85.3 80.1 65.8 95.7 52.2
21.0 88.0 77.5 72.1 96.1 51.8
28.1 90.0 73.6 84.0 96.4 51.5
35.2 ; 91.4 71.9 86.6 96.4 51.4
41.8 ' 92.6 70.0 90.3 96.5 51.4
47.1 93.3 69.5 92.6 96.5 51.4
53.7 : 94.1 68.4 96.2 96.8 51.4
67.7 95.3 67.0 96.9 97.0 51.4
70.2 95.5 66.8 97.2 97.1 51.5
80.1 95.8 66.5 97.7 97.4 51.5
83.6 95.9 66.4 100.0 100.0 51.6
89.4 96.1 66.3
№ 376 ВОДА-ИЗОМАСЛЯНАЯ [156] КИСЛОТА H2O-C4H8O2
X У t P
20.0 40.0 60.0 71.5 * 93.5 ** 91.4 93.0 93.9 I 94.3 20 13.9 15.6 16.7 17.2
* Верхний слон. ** Нижний слой.
317 № 377 ВОДА—ДИОКСАН [615]
H2O-C4H8O2
X У t P X У t P
0.0 0.0 25 23.8 60.0 63.7 25 47.7
10.0 38.9 37.0 70.0 66.2 47.7
20.0 49.9 42.9 80.0 69.7 47.5
30.0 55.5 45.8 90.0 76.8 45.2
40.0 58.8 47.3 100.0 100.0 36.9
50.0 61.4 47.7
№ 378 ВОДА—1,4-ДНОКСАН [994]
H2O-C4H8O.
X У t P X У t P
0.00 0.0 101.32 760 62.59 55.0 87.90 760
4.25 9.0 97.24 67.56 56.6 88.04
12.04 21.8 92.70 75.56 60.0 88.44
20.01 28.0 90.09 84.24 63.4 89.41 г
32.23 41.1 88.44 88.67 69.6 90.52 I
42.45 47.2 87.95 92.67 74.9 91.97
53.09 52.2 87.82 95.48 81.3 94.00
54.73 52.5 87.83 97.88 87.5 97.29
56.46 52.8 87.84 100.00 100.0 100.00
Примечание. Состав пара определен по графику, приведенному в статье.
А"» 379 ВОДА-1,4-ДИОКСАН [961]
H2O-C4H8O.
X У t P X У t P
0.0 0.0 101.07 760 79.7 ЪЪЛ 88.21 760
3.7 21.0 94.80 86.5 57.5 88.61
13.5 38.2 89.57 90.9 61.0 89.37
31.2 47.7 87.85 94.8 66.5 90.97
46.0 50.7 87.65 97.6 77.3 93.90
55.8 51.0 87.59 99.2 89.7 97.17
70.2 54.0 87.93 100.0 100.0 100.00
318 JVs 380 ВОДА-ДИОКСАН [685]
H2O-C4H8O2
X У t P jVi Y2
0.00 0.00 35 60.05 1.000
10.70 27.53 74.62 4.526 1.008
11.40 26.85 75.37 4.163 1.036
19.55 32.10 79.18 3.049 1.113
30.20 35.70 81.30 2.254 1.246
46.25 37.50 80.21 1.545 1.541
57.60 40.50 80.60 1.328 1.882
61.95 41.65 80.61 1.273 2.058
63.65 42.70 80.00 1.258 2.100
