Ðàâíîâåñèå ìåæäó æèäêîñòüþ è ïàðîì Êíèãà 1 - Êîãàí Â.Á.
Ñêà÷àòü (ïðÿìàÿ ññûëêà):
50 79.80 382.2
Ïðèìå÷àíèå. Ðàñ÷åòíûå äàííûå ïîäòâåðæäåíû ýêñïåðèìåíòàëüíî.
JVs 706 ÌÅÒÀÍ—ÝÒÈËÅÍ [32]
CH4—C2H4
X Ó t P, àòà X Ó t P, àòà
0.0 0.0 —145.9 0.03 16.1 90.0 —129.9 2.02
9.0 80.2 0.61 21.8 91.8 2.62
11.5 86.5 0.76 32.5 95.0 3.63
13.0 88.9 0.88 37.2 96.6 3.98
16.0 90.0 0.98 40.0 96.6 4.22
20.0 93.5 1.21 42.5 97.6 4.05
23.0 94.0 1.44 46.0 97.6 4.70
34.0 97.6 1.93 47.5 97.7 4.80
42.0 98.0 2.16 65.0 98.4 6.00
60.0 99.0 2.63 80.0 99.0 6.80
77.5 99.5 2.88 100.0 100.0 7.45
100.0 100.0 3.07 0.0 0.0 —114.9 0.49
0.0 0.0 —129.9 0.154 3.72 47.8 1.12
8.0 82.3 1.16 4.00 53.43 1.23
12.0 87.3 1.58 8.45 63.4 1.85
453Òàáëèöà JMs 675 (ïðîäîëæåíèå)
X Ó t Ð, àòà X Ó t Ð, àòà
9.42 67.0 —114.9 2.18 15.5 51.0 —69.9 12.3
14.45 83.5 3.27 22.0 65.7 15.1
27.63 90.0 5.00 26.14 67.0 16.6
43.66 93.5 7.74 28.5 68.0 18.4
61.9 95.8 10.4 34.5 70.4 21.2
77.3 96.8 12.2 36.1 76.1 23.1
84.5 98.0 13.5 40.9 76.4 25.6
86.4 98.5 13.8 44.0 77.2 27.6
100.0 100.0 14.6 0.0 0.0 —53.9 9.1
0.0 0.0 —97.1 1.3 4.5 16.5 11.0
5.7 45.8 3.0 5.9 21.6 11.7
9.2 62.2 4.1 12.0 37.6 13.9
12.1 63.5 5.0 16.7 46.0 15.8
27.5 80.4 9.1 24.8 54.0 21.3
48.4 86.7 14.6 27.0 56.7 23.2
60.0 90.0 17.6 31.0 61.2 26.2
70.3 93.4 20.3 33.8 62.1 27.4
100.0 100.0 27.5 0.0 0.0 —37.9 15.0
0.0 0.0 —86.9 2.45 5.6 10.4 16.8
4.6 25.0 4.4 9.2 19.6 18.8
11.6 62.4 6.8 14.3 24.3 21.2
22.6 76.9 11.0 19.3 27.7 24.0
27.8 80.0 13.3 26.4 33.0 28.8
36.0 85.0 16.0 0.0 0.0 —19.9 24.8
45.6 86.6 17.7 8.15 16.1 27.4
59.1 88.4 22.0 16.0 22.2 29.6
68.1 .92.2 25.8 20.8 26.6 31.2
76.5 94.9 28.9 25.6 30.0 33.5
100.0 100.0 39.6 30.2 34.2 37.4
0.0 0.0 —69.9 5.06 36.1 36.6 43.6
10.1 30.0 9.5
JVs 707 METAH- -ÝÒÈËÅÍ [578]
CH4—C2H4
X Ó t Ð, àòà X Ó t Ð, àòà
5.5 60.0 —78 5 73.5 94.0 —78 40
16.0 79.0 10 80.0 92.5 50
29.0 87.0 15 82.0 90.5 55
42.5 90.0 20 86.0 86.0 60
62.0 93.0 30
Ïðèìå÷àíèå.  ðàáîòå ïðèâîäÿòñÿ òàêæå êðèâûå ðàâíîâåñèÿ ïðè —104, —88, —42° è 0°.J4S 708 ÌÅÒÀÍ—ÀÖÅÒÀËÜÄÅÃÈÄ [283]
CH4—C2H4O
X Ó t P, àòà X Ó t Ð, àòà
2.2 95.35 1 10 12.3 96.60 20 60
4.9 96.70 20 14.1 96.83 70
7.0 97.50 30 15.6 96.87 80
9.1 97.92 40 17.2 96.90 90
11.1 98.16 50 2.0 — 40 10
13.0 98.30 60 4.0 89.30 20
14.7 98.38 70 5.9 90.95 30
16.2 98.41 80 7.7 92.50 40
18.2 98.44 90 9.4 93.78 50
2.15 92.00 20 10 11.2 94.78 60
4.6 93.50 20 12.7 94.82 70
6.7 94.60 ÇÎ 14.1 94.95 80
8.6 95.58 40 15.5 94.98 90
10.6 96.25 50
JYs 709 ÌÅÒÀÍ—ÝÒÀÍ [934]
CH4- -C2H6
X Ó t P, àòà X Ó t Ð, àòà
1.7 25.8 — 60 5 9.0 45.2 — 40 15
4.0 50.0 — 70 13.5 60.1 — 50
7.0 65.7 — 80 18.3 72.0 — 60
10.5 77.0 — 90 23.7 81.6 — 70
14.6 85.6 —100 29.8 88.6 — 80
21.3 91.4 —110 37.2 93.9 — 90
32.9 95.7 —120 48.6 97.3 —100
56.0 98.7 —130 68.5 99.5 —110
2.5 19.5 — 40 10 1.1 6.6 — 10 20
6.0 40.9 — 50 5.8 33.0 — 20
9.6 57.4 — 60 10.7 51.4 — 30
13.6 70.1 — 70 16.1 65.0 — 40
18.2 81.0 — 80 22.0 75.0 — 50
23.9 89.0 — 90 28.2 82.3 — 60
30.9 95.1 —100 35.0 88.1 — 70
43.8 97.5 —110 43.3 92.5 — 80
69.5 99.4 —120 54.5 96.3 — 90
0.9 4.2 — 20 15 71.5 98.9 —100
4.6 26.4 — 30
JYs 710 METAt [—ÝÒÀÍ [503]
CH4- -C2He
X Ó t Ð, àòà X Ó t Ð, àòà
5.00 —60.0 6.8 14.92 —48.4 6.8
— 5.00 —45.2 30.02 _ —104.8
14.92 — —84.9 — 30.02 —50.4
455Òàáëèöà «Ns 798 (ïðîäîëæåíèå)
X Ó t Ð, àòà X Ó t Ð, àòà
50.02 —118.9 6.8 85.16 —106.1 17.0
— 50.02 —62.7 — 75.16 —70.7
70.00 — —122.7 92.50 — —108.7
— 70.00 —74.6 — 92.50 —84.3
85.16 .— —128.6 97.50 — —110.4
— 85.16 —88.9 — 97.50 —99.1
92.50 — —130.2 5.00 — —17.1 20.4
— 92.50 —100.1 — 5.00 —8.1
97.50 — —131.3 14.92 — —38.0
— 97.50 —114.6 - 14.92 —12.9
5.00 — —45.0 10.2 30.02 — —62.4
— 5.00 —32.6 ¦— 30.02 —20.7
14.92 — —69.3 50.02 — —83.3
— 14.92 —36.6 — 50.02 -33.1
30.02 — —90.7 70.00 — —94.8
— 30.02 —42.7 — 70.00 -49.4
50.02 — —107.1 85.16 — —100.8
— 50.02 —52.3 — 85.16 —67.1
70.00 — —115.2 92.50 — —103.7
— 70.00 —66.1 — 92.50 —80.8
85.16 — —119.4 97.50 — —105.4
— 85.16 —81.1 — 97.50 —94.4
92.50 — —121.3 5.00 — —10.2 23.8
— 92.50 —93.7 — 5.00 —2.1
97.50 — —122.8 14.92 — —30.2
— 97.50 —108.2 —. 14.92 —7.3
5.00 — —33.9 13.6 30.02 — —55.1
— 5.00 —22.9 — 30.02 -15.4
14.92 — —56.8 50.02 — -77.2
— 14.92 —27.3 — 50.02 —28.4
30.02 — —80.0 70.00 — -89.4
.— 30.02 -33.9 — 70.00 -45.5
50.02 — —97.7 85.16 — -96.0
— 50.02 —40.2 — 85.16 —67.1
70.00 — —107.3 92.50 — —99.1
— 70.00 —59.4 — 92.50 —77.8
85.16 — —112.2 97.50 — —101.1
— 85.16 —75.3 — 97.50 —92.4
92.50 — —114.4 5.00 — -4.0 27.2
— 92.50 —88.4 — 5.00 +3.4
97.50 — —116.1 14.92 — —23.1
— 97.50 —103.1 — 14.92 -2.3
5.00 — —24.8 17.0 30.02 — -48.3
— 5.00 —14.9 — 30.02 —10.8
14.92 _ —46.8 50.02 — —71.6
— 14.92 —19.5 — 50.02 —24.3
30.02 — —70.8 70.00 — —84.7
— 30.02 —26.8 — 70.00 —42.3