Равновесие между жидкостью и паром Книга 1 - Коган В.Б.
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КИСЛОТА КИСЛОТА
CHCI3-C2H4O2 CHCI3-C2H4O2
X У I P X У t P
0.0 0.0 25 15.7
0.0 0.0 118.1 760 4.90 43.97 _
3.00 21.51 106.8 8.49 _ 46.4
3.00 26.42 101.7 10.67 _ 51.3
8.10 33.80 101.3 13.37 _ 58.6
11.72 45.15 95.7 14.87 69.46 —
12.22 45.68 95.4 17.79 74.62 —
18.63 57.85 88.8 19.48 78.97 —
28.14 70.61 81.4 20.78 _ 77.4
40.08 80.58 74.4 26.36 81.40 —
50.62 85.72 70.5 28.14 _ 93.5
52.56 88.02 69.9 31.34 — 101.7
61.27 90.88 67.8 36.34 87.44 \ —
75.07 94.28 64.9 44.95 89.44 \ _
100.0 100.0 61.2 52.56 74.62 — 141.1 173.5 ХЛОРОФОРМ—ДИХЛОРЭТАН CHCl3—C2H4Cl2
[100]
У t P X У t
0.0 83.28 760 55.0 75.0 68.85
10.0 81.90 60.0 79.0 67.72
18.0 80.50 65.0 83.0 66.66
26.0 79.14 70.0 86.0 65.86
34.0 77.75 75.0 89.0 65.00
41.0 76.40 80.0 91.0 64.17
48.0 75.05 85.0 93.0 63.45
55.0 73.00 90.0 95.0 62.68
61.0 72.48 95.0 98.0 61.99
67.0 71.20 100.0 100.0 61.05
71.0 70.02
1,1 -ДИХЛОРЭТАН—ХЛОРОФОРМ C2H4Cla—CHCl3
[88]
X У t P X У t P
0 0.0 61.30 760 60 65.7 58.95 760
10 15.2 60.90 70 77.0 58.53
20 25.2 60.45 80 86.0 58.12
30 36.0 60.05 90 93.5 57.65
40 46.7 59.65 100 100.0 57.17
50 56.0 59.30
№ 628 ХЛОРОФОРМ—ЭТИЛОВЫИ СПИРТ [94',]
CHCl3-C2H6O
X У t P X У t P
0.00 0.00 35.0 102.78 38.45 73.70 35.0 253.39
0.62 2.54 104.87 39.22 74.12 255.28
2.41 9.91 111.31 43.84 76.46 267.65
2.97 12.10 113.61 48.27 77.97 274.04
5.42 21.54 123.54 61.85 81.81 291.95
5.94 23.43 125.82 67.83 83.27 296.93
11.09 38.85 148.26 77.46 85.54 303.05
17.30 53.04 177.60 82.65 86.98 305.39
23.61 62.07 205.68 84.23 87.52 305.12
28.73 67.47 225.06 84.83 87.83 306.25
30.14 68.70 229.24 93.15 91.61 306.05
32.27 70.09 236.50 95.60 93.63 304.87
423 Таблица JVs 617 (продолжение)
X У t P X У I P
95.86 93.85 35.0 304.17 97.58 95.79 45.0 443.07
96.00 94.03 303.69 98.66 97.27 439.89
96.16 94.14 303.91 100.00 100.00 433.54
100.00 100.00 295.11 0.00 0.00 55.0 279.86
0.00 0.00 45.0 172.76 3.31 11.62 306.38
1.57 6.00 180.96 7.12 23.02 339.89
1.89 7.16 182.63 8.02 25.33 346.89
4.76 17.17 199.62 10.29 31.23 367.01
7.12 24.67 214.44 14.79 40.35 407.90
12.60 39.74 249.92 18.69 47.95 441.04
19.97 53.66 298.08 22.01 52.71 469.41
20.11 53.95 299.63 28.06 59.42 508.78
25.69 60.60 329.62 34.12 64.07 543.53
31.16 65.57 355.66 34.45 64.19 545.72
32.98 67.14 365.07 37.67 66.41 560.25
40.15 71.43 391.51 39.04 67.20 566.74
44.39 73.40 403.91 39.65 67.60 569.02
51.40 76.03 420.63 47.94 71.61 599.03
54.05 77.03 425.28 57.30 75.27 623.67
62.83 79.54 438.89 62.11 76.39 632.14
71.48 81.91 448.17 78.51 78.57 641.49
82.06 85.16 455.56 72.69 80.10 646.79
88.52 87.83 455.79 77.64 81.81 650.96
91.00 89.33 454.54 83.90 84.17 653.11
91.25 89.46 454.02 90.37 87.98 650.38
91.63 89.74 453.76 94.30 91.50 644.24
95.57 93.19 448.49 96.52 94.08 626.79
96.77 94.54 445.38 100.00 100.00 617.84
JVs 629 ХЛОРОФОРМ—ЭТИЛОВЫЙ СПИРТ [583]
CHCl3-C2H6O
X У t P X У t P
0.00 0.00 55 279.9 26.6 58.9 55 500.0
1.00 3.85 287.7 33.4 63.3 540.0
1.28 4.68 290.0 42.4 68.9 580.0
2.40 9.05 300.0 58.05 74.5 620.0
4.90 16.5 320.0 91.7 88.9 648.8
7.25 23.9 340.0 94.9 92.2 642.6
11.75 34.8 380.0 96.75 94.0 636.4
16.25 44.6 420.0 99.0 98.0 624.0
21.0 51.3 460.0 100.0 100.0 617.8 ХЛОРОФОРМ—ЭТИЛОВЫЙ СПИРТ CIIClo—СоПдО
[100]
X У t P Yi Ya
2.1 8.3 45 184.4 1.712 1.003
' 6.5 23.8 211.0 1.800 0.999
15.8 47.3 261.0 1.855 0.974
21.3 55.7 302.5 1.822 0.985
25.9 60.7 327.4 1.765 1.003
30.6 65.1 350.6 1.711 1.017
34.5 67.8 376.5 1.657 1.042
38.6 70.4 382.9 1.603 1.064
2.1 7.5 55 296.0 1.728 1.002
10.6 32.1 368.5 1.815 1.000
16.0 42.8 412.7 1.802 1.003
21.1 51.3 454.7 1.802 0.998
25.9 57.2 490.0 1.763 1.011
30.3 61.6 519.9 1.716 1.018
34.3 64.7 541.2 1.658 1.032
38.5 67.0 562.2 1.587 1.071
ХЛОРОФОРМ—ЭТИЛОВЫЙ СІІИРГ CHCl3-C2H6O
[173]
X У t P X V t P
0.0 0.0 78.30 760 50.6 70.7 61.50 760
7.5 20.3 74.60 63.3 75.2 60.15
15.6 37.5 70.95 69.3 77.0 59.75
20.4 45.9 68.85 * 80.7 82.3 59.25
23.0 49.9 67.90 83.1 83.4 59.20
26.5 53.3 66.90 89.5 87.2 59.55
29.5 56.9 65.90 98.0 95.0 60.50
38.2 64.5 63.60 100.0 100.0 61.20
№ 632 АЦЕТОН—ХЛОРОФОРМ [1097]
C3II6O-CHCl3
X У I P X У t P
0.00 0.00 35.17 293.1 33.90 31.83 35.17 248.8
8.21 5.00 279.5 41.88 43.68 248.4
8.25 4.65 280.1 44.69 47.63 249.4
19.53 14.64 262.6 44.84 47.96 250.8
20.03 14.34 261.9 48.57 53.43 252.8
33.65 31.71 249.2 48.72 53.65 252.7
425 Таблица JNIs 642 (продолжение)
X У t P X V t P
49.17 54.43 35.17 252.9 71.16 80.83 35.17 286.1
50.61 56.25 255.4 72.96 82.73 290.5
50.70 56.40 255.7 73.43 82.62 291.6
57.52 65.83 263.1 81.47 89.61 307.3
57.68 66.24 263.2 81.82 89.71 308.0
59.50 68.17 266.9 87.68 93.62 319.7
60.34 68.68 267.4 87.97 93.77 320.1
63.36 72.71 272.2 93.97 97.15 332.1
63.94 73.54 273.1 94.12 97.24 332.4
64.32 73.98 273.5 100.0 100.0 344.5
