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GB: Deciinax® (Roche)
USA: Deciinax® (Roche)
Decamethonium-bromid 541-22-0
Muskelrelaxans
decamethyienebis(trimethylammonium bromide)
2 (H3O3N
Br-{CH2)l0-Br
Trimethyl- 1,10-Dibromdecan amin
I(H3O3N — (CH2)10— N(CH3)3 J 2 Br" I Decamethonium-bromid
A. T. Blomquist et al., J. Am. Chem. Soc. 81,678 (1959). USA: Syncurine® (Burroughs Wellcome)
Deferoxamin
(Desferrioxamine)
70-51-9 138-14-7
Methansulfonat
Eisenkomplexbildner (zurTherapie von Eisenspeicher-krankheiten)
N-[5-[3-[(5-aminopentyl)hydrocarbamoyl]propionamido]pentyl]-3-[[5-(/V-hydroxyacetamido)pentyl] carbamoyl]propionohydroxamic acid
■o-°
z —ci
Chlorameisen-
saurebenzylester
+ H2N-(CH2)5-N02
l-Amino-5-nitro-pentan
2-NH~(CH2]s-N02
C2Hs0H /NhUCl/Zn-Staub
0 /Pyridm
Z-NH-!CH2)5-NH ----*
c 1 eemstemsaure-
OH anhydrid
1- Benzyloxycarbonyl -amino-5-hydroxyl-aminopentan s (T)
Z-NH-(CH2)5--N-C-CH2-CH2-COOH HO 0
Deferoxamin - Dehydrocholsaure D 269
Z-NH-(CH2)s —
2-[5-Benzy(oxycarbonyl-aminopentyl)-3,6-dioxo-\ etrahyd ro - \ 2 - oxa zin
л /Tn ICHjCOJzO/Pyndin _ Hj/Pd-C
2 CD --* Z-NH~-(CH2)5-N-C-CH3 -J-*• H2N-(CH2)5-N-C-CH3
но о HO 0
) - Amino -5-1N -acetylhydroxyl-aminoj-pentan s £3)
THF^Ruckftufl
Z-NH-(CH2)s-N-C~(CH2)2-C-NH-(CH2]5-N-C-CH3 IN II I II
HO 0 0 HO 0
H2>Pd— С (2) ! THF/Ri'ickHuR
-- H2N“tCH2)B-N-C-(CH2)2-C-MH-(CH2|5-N-C-CH3 ^ ^
НО О О НО О
H2N—fCH2)s—N-C —(CH2)2-C-NH-(CH2J5-N-C-(CH2}2-C--NH-(CH2l5-N-C-CH3
I II II I II II I II
НО О О НО О О НО О
Isolierung aus Stoffwechselprodukten von Actinomyceten:
H. Bickel ct al., Helv. Chim. Acta. 43,2118 (1960).
Konstitutionsaufklarung:
H. Bickel et al., Helv. Chim. Acta 43,2129 (1960).
Synthese:
Belg-P 609053 (Ciba; Anm. 11.10.1961; CH-Prior. 11.10.1960, 23.11.1960, 7.4.1961, 26.4.1961, 29.6.1961,10.8.1961,11.8.1961).
Belg-P 619532 (Ciba; Anm. 28.6.1962; CH-Pnor. 29.6.1961).
V. Prelog u. A. Walser, Helv. Chim. Acta 45,631 (1962).
D: Desferal® (Ciba) I: Desferal® (Ciba)
F: Desferal® (Ciba-Geigy) J: Desferal® (Ciba-Geigy-Takeda)
GB: Desferal® (Ciba) USA: Desferal® (Ciba)
Dehydrocholsaure
(Dehydrocholic acid;
Acide d6hydrocholique)
81-23-2
Cholereticum;
Leberschutzmittel
3,7,12-trioxocholanic acid
но
COOH
Ct2/NaOCOCH3/CH3COOH
Chots'aure
270 D Dehydrocholsaure - Demecarium-bromid - Demeclocyclin
USP 2 966 499 (Merck & Co.; ert. 27.12.1960; Prior. 9.4.1958).
D: Decholin® (Cassella-Riedel) Eupond®N (Ferring)
FeJacomp® (Verla)-Komb.
F; Dycholium® (ТёгарИх)
GB: Dehydrocholin® (Duncan, Flockhart) I: Cherocolina® (Negroni)
Decholin® (Albert-Farma) Deidrocolico® Vita (Vita) Deidrocolit® (Fabo)
Dicolan® (Biologici)
Didrocolo® (Recordati) zahlr. Komb.-Prap.
J: Dehychol® (Eiken-Tanabe)
Dehydrochol® (Kanto; Sawai; Hokuriku) Hydrochul® (Kyorin)
USA: Cholan-DH®(Pennwalt)
Cholan-HMB® (Pennwalt)-Komb. Cholan® (Pennwalt)-Komb.
Decholin® Sodium (Dome) Gastroenterase® (Wallace)-Komb. Ketochol® (Searle)
Neocholan® (Dow)
Sodium Dehydrocholate (Endo)
Demecarium-bromid 56-94-0 Cholinesteraseinhibitor;
Vagotonicum
(m-hydroxyphenyl)trimethylammonium bromide decamethylenebis(methylcarbamate) ester
2 C0C|2 Phosgen
CH3 CH3
HN-{CH2),0-NH
VO-Bis-lmethyl-amino}-decan (W,W'-Dimethyl-deeamethylen-1,10-diamin)
CH3 CH3
Ci-CO-N~(CH2)jo-N-CO-Cl
XX
3-Dimethylammo-phenol (Na-Salz)
(H3C)2N.
CH3 СНз
O-CO-N-fCHzJic-N-CO-O^^NICH^
Methyh
bromid
CH3Br
СНз СНз
1НзС)зЙ^^.О — CO —N —(CHjIiq —N —CO— O^^r^NIC H3)3
и XT
Demecarium-bromid
USP 2 789891 (Osterr. Stickstoffwerke; ert. 1957; A-Prior. 1954).
D: Tosmilen® (Lentia)
F: Tosmilene® (Chibret) GB: Tosmilen® (Astra)
J: Tosmilen® (Chugai)
USA: Humorsol® (Merck Sharp & Dohme)
Demeclocyclin
(Demethylchlortetracyclin)
127-33-3 64-73-3
Antibioticum
Hydrochlorid
7-chloro-4-(dimethylamino)-l,4,4a,5,5a,6,ll,12a-octahydro-3,6,10,12,12a-pentahydroxy-l,l 1-dioxo-2-naphthacenecarboxamide
Demeclocyclin - Demegeston D 271
Aus Fermentationslosungen einer Mutante von Streptomyces aureofaciens USP2 878 289 (American Cyanamid; ert. 17.3.1959; Prior. 28.5.1956). USP 3 012 946 (American Cyanamid; ert. 12.12.1961; Anm. 16.11.1960). USP 3 019 172 (American Cyanamid; ert. 30.1.1962; Anm. 14.3.1960). USP 3 050446 (American Cyanamid; ert. 21.8.1962; Anm. 28.7.1960). USP 3 154 476 (Olin Mathieson; ert. 27.10.1964; Anm. 29.4.1963). DBP 1041213 (American Cyanamid; Anm. 24.5.1957;USA-Prior. 28.5.1956). J. R. D. McCormick et al., J. Am. Chem. Soc. 79,4561 (1957).
D: Demebronc® (Lederle)-Komb. Ledermycin® (Novalis Arzn.) Lederstatin® (Novalis Arzn.)-Komb. F: Ledermycine® (Lederle-Novalis) Mexocine® (Specia)
GB: Ledermycin® (Lederle)
I: Actaciclina®(Courtois)
Bioterriclin® (Lisapharma) Clortetrin® (Medosan) Deme-Proter® (Proter)
Demeplus® (Boniscontro 4- G.) Demetetra® (Pierrel)
Demetraclin® (Weles) Demetraciclina® (Libral)
Detracin® (Sierochimica)
Detravis® (Vis)
Dimeral® (Panther-Osfa Chemie)
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