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. .: , 2007. 608 c.
ISBN 5-98657-009-
( ): pharmazeutischewirkstoffe1982.djvu
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Percutina® (Mitim)
Prodermin® (Eufarma)
Radiocin® (Radiumfarma)
Roliderm® (Neopharmed) Sterolone® (Francia Farm.) Straderm® (Ita)
Topifluor® (Tiber)
Ultraderm® (Ecobi)
J; Benamizol® (Mohan Yakuhin) Biscosal® (Ohta Seiyaku)
Cortiphate® (Tokyo Tanabe Seiyaku) Flucort® (Syntex-Tanabe)
Fluvean® (Kowa)
Fluzon® (Taisho Seiyaku)
USA: Fluonid® (Marion)
Neo-Synalar® (Syntex)-Komb. Synalar® (Syntex)
Synemol™ (Syntex)
Fluocinonid 356-12-7 Glucocorticoid
6a,9-difluoro-11Ц 16a, 17,21 -tetrahydroxypregna-1,4-diene-3,20-dione, cyclic 16,17-acetal with acetone, 21-acetate
416 F Fluocinonid - Fluocortinbutyl
DOT7,207 (1971).
GB-P 916 996 (Olin Mathieson; Anm. 21.7.1959; USA-Prior. 6.8.1У58).
USP 3124 571 (Syntex; ert. 10.3.1964; Anm. 19.5.1960; MEX-Prior. 26.1.1960).
D: Topsymm® (Gruneniha/) Topsyn® (Recordati)
Topsyn® (Griinenthal) J: Bestasone® (Kodama)
F: Topsyne® (Cassenne) Topsym® (Syntex-Tanabe)
GB: Metosyn® (ICI) USA: Lidex® (Syntex)
I: Flu 21®(Lanat) Topsyn® (Syntex)
Fludex® (San Carlo) Lidex® E Cream (Syntex)
FlllOCOrtinbUtyl 41767-29-7 Glucocorticoid
(Fluocortin butylester) 33124-50-40 Fluocortin
6a-fluoro-ll/J-hydroxy-16a-methy]-3,20-dioxopregna-l,4-dien-21-oic acid ester with butanol
Fluocortinbutyl
DOF2,669(1977).
DOT 13,528(1977).
DOS 2 150268 (Schering AG; Anm. 4.10.1971).
DOS 2 204 361 (Schering AG; Anm. 27.1.1972).
DOS 2260 303 (Schering AG; Anm. 6.12.1972).
GB-P 1 387911 (Schering AG; Laufzeit ab 19.3.1975; D-Prior. 4.10.1971, 27.1.1972).
H. Laurent et al., Arzneim. Forsch. 27, (II), 2187 (1977) (auch andere Verfahren).
DOS 2441 284 (Schering AG; Anm. 27.8.1974).
Belg-P 823 682 (Schering AG; Anm. 20.12.1974; D-Prior. 21.12.1973,27.8.1974, 16.9.1974).
D: Vaspit® (Schering)
Fluocortolon F 417
Fluocortolon
152-97-6
Glucocorticoid
6а-Яиого-11Д 21 -dihydroxy-16a-methylpregna-l,4-diene-3,20-dione
h3c-co-o-ch2.
21-Acetoxy-3/3-hydroxy-
I6a-methyl-20-oxo-
5-pregnen
[aus 30-Hydroxy-16a-methyl-20-oxo-5-pregnen]
H2F2
W-Brom- Fluor-succinimid wasser-
н3с-со-о-сн2ч
■c=Q
ChromlVD-ox id
Н4С-СО-О-СН,.
H3C-C0-0-CH2.
mikrobiologische Hydroxylierung [Curvuiana tunatb ]
HO-CH2
mikrobiotogische Dehydrierung
[ Corynebaztenum simplex Oder Bacillus Lentus ]
4c=o
Fluocortolon
DBP 1 135899 (Schering AG; Anm. 20.5.1960).
Belg-P 614 196 (Schering AG; Anm. 21.2.1962; D-Prior. 22.2.1961). A. Domenico et al., Arzneim. Forsch. 15,46 (1965).
DBP 1169444 (Schering AG; Anm. 22.2.1961). Ausgangsverbindung:
V. Petrov, D. M. Williamson, J. Chem. Soc. 1959,3595.
Weiteres Verfahren:
K. Kieslich et al., Justus Liebigs Ann, Chem. 726,168 (1969).
DOS 1 909152 (Schering AG; Anm. 19.2.1969).
Obersicht:
A. A. Akhrem et al., Russ. Chem. Rev. 34, 926 (1965).
D: Syracort® (Beiersdorf)-Komb. Ultralan® oral (Schering) Ultralan® Salbe (Schering)-Komb. F: Myco-Ultralan® (SEPPS)-Komb. Ultraian® (SEPPS)-Komb.
Ultralanil® Pommade grasse (SEPPS)-Komb. GB: Ficoid® 5 plus (Fisons)-Korab. ..
Ultralanum® (Schering Chem.)-Komb.
I: Ultralan® orale (Schering)
418 F Fluocortoloncapronat - Fluocortolontrimethyl-acetat - Fluorometholon
Fluocortoioncapronat
303-40-21 Glucocorticoid
6cr-f]uoro-llA2]-dihydroxy-16a-methylpregna-l,4-diene-3,20-dione-21-hexanoate H0-CH2.
(HjjCg COijO
h1,c5-co-o-ch2n
c=^0
Fluocortolon
Capronsaureanbydrid
Fluocortoloncapronat
DOT 9, 344 (1973).
FP 1 561 884 (Schering AG; Anm. 10.5.1968; D-Prior. 13.5.1967).
D: Ultracur® (Schering)-Komb.
Ultralan® Creme (Schering)-Komb. Ultralan® KristaJlsusp. (Schering) Ultralan® Salbe (Schering)-Komb. Ultraproct® (Schering)-Komb.
F: Myco-UJtralan (SEPPS)-Komb. Ultralan® (SEPPS)-Komb.
Ultraianif® (SEPPS)-Komb. Ultraproct® (SEPPS)-Komb.
GB; Ficoid® (Fisons)-Komb.
Ultradtl® (Schering Chem.)-Komb. Ultralanum® (Schering Chem.)-Komb. Ultraproct® (Schering Chem.)-Komb.
Fluocortolontrimethyl- гозво-ю-з acetat
(Fluocortolon-21 -pivalat)
Glucocorticoid
6a-fluoro-ll^,21-dihydroxy-16a-methylpregna-l,4-diene-3,20-dione-21-trimethylacetate HO-CH,, Г(Н3С)3С-С0-0-СН2
1(Н3С)3С-СО]гО
NaOH Жг0/С1-СНг-СН:-а
Pivalinsaureanhydnd
VssO
Fiuocortolontrimethylacetat
DOT 9,345 (1973).
FP 1561 884 (Schering AG; Anm. 10.5.1968; D-Prior. 13.5.1967),
D: Ultracur® (Schering)-Komb.
Ultralan® Creme (Schering)-Komb. Ultraproct® (Schering)-Komb.
F: UltralaniT® (SEPPS)-Komb.
Ultraproct® (SEPPS)-Komb. GB; Ficoid® 5 (Fisons)
Ultraproct® (Schering Chem.)
Fluorometholon 426-13-l Glucocorticoid
9a-fluoro-ll/3,17a-dihydroxy-6a-methylpregna-l,4-diene-3,20-dione
Fluorometholon - Fluorouracil F 419
HO-CH,
2xc=o
* ' > + H3C-S02-C1
9a-Fluor-6a-methyl- Methansulfonyl-hydrocortlson chlorid
[aus 3,20-0io>(o-6a-methy(-110, 17, 2t - tr ihydroity-4- pregntr ]
H3C-S02-0-CH2 HO.
Ыа1 /ИэС-СО-СН3 ^
Natrium -jodid
\r—-0 mikrobiologische Oehydrierung [Septomyxa affmis (ATCC 6737)1
CH3
Fluoromethoion
USP 2 867 638 (Upjohn; ert. 6.1.1959; Anm. 17.5.1967; Prior. 10.9.1956). DBP 1 056 605 (Upjohn; Anm. 6.5.1959; USA-Prior. 10.9.1956). Ausgangsverbindung:
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